Open Outlook 2013, then click on File and choose Add Account.
I f you prefer to set up your Office 365 email account manually or wish to confirm the local settings for your setup, you can use the settings below. When the account is set up, you’ll receive a message confirming it was done successfully. Outlook can recognize an exchange email account and will create the account without requiring you to enter the server settings manually. Fill out the information needed, including the name that you’d like to appear when sending emails, new email address, and password, then click Next. The Auto Account Setup screen will appear.
Thanks to this resource for getting this working for me! I've basically just updated, consolidated and expanded on answers given.This tutorial describes how to add Microsoft 365 email to Outlook 2013. I’m not strictly sure you need to run Outlook as an administrator in the above, but it now works without being run as an administrator so I’m happy.
Macros should now work! I'm using them as part of an email rule and this now processes perfectly. Either now, or after you go “Developer -> Visual Basic” again, a window should pop-up prompting you about the newly signed macro – I clicked remember and don’t prompt again. Restart Outlook.exe again as Administrator. 
Close Outlook, and choose Yes to save the VBA project. Click to save the macro in VBA – actually click the save button in VB ( bizarrely it breaks if you don’t expressly save here). Select OK to select “Self Cert” (VB then shows the project as being signed with this certificate) then click OK again accept and close the window. Select Tools -> Digital Signature -> Choose. Open your module containing the VBA code. Run certmgr.crt from the start menu and copy “Self Cert” from “Personal\Certificates” to the “Trusted Root Certification Authorities\Certificates” folder. Create a self cert – I called mine “Self Cert” (generated from here in Office 2013 - C:\Program Files (x86)\Microsoft Office\Office15\SELFCERT.EXE). Having come across this just now, this is how I ultimately solved it (none of the other suggestions worked for me):
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